First osmium-catalysed ketamination of alkenes
Literature Information
Amparo Villar, Claas H. Hövelmann, Martin Nieger, Kilian Muñiz
Conditions for a first oxidative conversion of alkenes into 2-amino ketones are described, which yield racemic products within a direct oxidation pathway and 2-amino ketones with up to 99% enantiomeric excess from the corresponding enantiopure amino alcohols.
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