Catalyst-free sulfonylation of activated alkenes for highly efficient synthesis of mono-substituted ethyl sulfones in water

Literature Information

Publication Date 2014-07-10
DOI 10.1039/C4GC00932K
Impact Factor 10.182
Authors

Yu Yang, Lin Tang, Sheng Zhang, Xuefeng Guo, Zhenggen Zha, Zhiyong Wang


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Abstract

A catalyst-free sulfonylation reaction of activated alkenes with sulfonyl hydrazides was efficiently developed under mild and environmentally benign conditions, in water without any ligand or additive. The reaction gave a range of structurally diverse mono-substituted ethyl sulfones with excellent yields, in which the by-product was nitrogen.

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