Photochromism of diarylethene single crystals: crystal structures and photochromic performance
Literature Information
Masakazu Morimoto, Masahiro Irie
Diarylethenes undergo thermally irreversible and fatigue-resistant photochromic reactions not only in solution but also in the single-crystalline phase. This article describes recent development of the single-crystalline photochromism of diarylethene derivatives. We focused on the relationship between their crystal structures and the photochromic performance. Photocyclization/cycloreversion quantum yields, absorption spectra, the absorption anisotropies, and surface morphology changes are strongly dependent on the conformations and packing structures of the molecules in the crystals.
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