Asymmetric Carroll rearrangement of allyl α-acetamido-β-ketocarboxylates catalysed by a chiral palladium complex
Literature Information
Ryoichi Kuwano, Naoki Ishida, Masahiro Murakami
Asymmetric decarboxylative rearrangement (Carroll rearrangement) of allyl α-acetamido-β-ketocarboxylates was catalysed by a palladium complex modified with a chiral phosphine ligand, giving optically active γ,δ-unsaturated α-aminoketones with up to 90% ee.
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