Making crystals from crystals: a green route to crystal engineering and polymorphism

Literature Information

Publication Date 2005-06-15
DOI 10.1039/B504668H
Impact Factor 6.222
Authors

Dario Braga, Fabrizia Grepioni


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Abstract

Supramolecular reactions between crystalline materials as well as reactions between a crystalline material and a vapour can be used to generate new crystalline substances. These solvent-free processes can be exploited to prepare both hydrogen-bonded co-crystals and coordination networks. Solid–vapour reactions do not differ from solid–vapour uptake/release processes, and can also be used to prepare polymorphs and solvates. It is argued that solvent-less reactions involving molecular crystals represent a green route to supramolecular solid-state chemistry and crystal engineering.

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