Synthesis of a four-coordinate titanium(iv) oxoanionvia deprotonation and decarbonylation of complexed formate‡

Literature Information

Publication Date 2005-06-09
DOI 10.1039/B504492H
Impact Factor 6.222
Authors

Arjun Mendiratta, Joshua S. Figueroa, Christopher C. Cummins


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Abstract

Deprotonation of the titanium formate complex [Ar(t-Bu)N]3TiOC(O)H with LiN(i-Pr)2 resulted in the release of free CO and the formation of a titanium(IV) oxoanion complex, isolated as its lithium salt.

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