[{(Mo)Mo5O21(H2O)3(SO4)}12(VO)30(H2O)20]36−: A molecular quantum spin icosidodecahedron

Literature Information

Publication Date 2005-05-27
DOI 10.1039/B504491J
Impact Factor 6.222
Authors

Bogdan Botar, Paul Kögerler, Craig L. Hill


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Abstract

Self-assembly of aqueous solutions of molybdate and vanadate under reducing, mildly acidic conditions results in a polyoxomolybdate-based {Mo72V30} cluster compound Na8K16(VO)(H2O)5[K10⊂{(Mo)Mo5O21(H2O)3(SO4)}12(VO)30(H2O)20]·150H2O, 1, a quantum spin-based Keplerate structure.

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