(Z)-Selective cross-dimerization of arylacetylenes with silylacetylenes catalyzed by vinylideneruthenium complexes
Literature Information
Hiroyuki Katayama, Hiroshi Yari, Masaki Tanaka, Fumiyuki Ozawa
The vinylideneruthenium(II) complexes bearing bulky and basic tertiary phosphine ligands, RuCl2(CCHPh)L2 (L = PPri3, PCy3), serve as good catalyst precursors for (Z)-selective cross-dimerization between arylacetylenes and silylacetylenes in the presence of N-methylpyrrolidine.
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