A readily prepared neutral heterobimetallic titanium(iv)–rhodium(i) catalyst for intramolecular hydroacylation

Literature Information

Publication Date 2005-06-01
DOI 10.1039/B504195C
Impact Factor 6.222
Authors

John P. Morgan, Kousik Kundu, Michael P. Doyle


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Abstract

The combination of HOCMe2CH2PPh2, Ti(OiPr)4, and [Rh(cod)Cl]2 (3∶1∶1) in either benzene or dichloromethane produces a discrete species (tentatively formulated as complex 14) that is an active catalyst for intramolecular hydroacylation reactions of 3-substituted pentenals.

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