The first rare earth organometallic complex of 1,4,7-trithiacyclononane: a precursor to unique cationic ethylene and α-olefin polymerisation catalysts supported by an all-sulfur donor ligand

Literature Information

Publication Date 2005-06-01
DOI 10.1039/B503967C
Impact Factor 6.222
Authors

Cara S. Tredget, Fanny Bonnet, Andrew R. Cowley, Philip Mountford


View Original

Abstract

[Sc([9]aneS3)(CH2SiMe3)3], the first rare earth organometallic complex of 1,4,7-trithiacyclonane, is a precursor to ethylene and α-olefin polymerisation catalysts upon activation with BArF3 or [CPh3][BArF4] (ArF = C6F5); these are the first cationic rare earth organometallic catalysts supported by an all-sulfur donor ligand.

Related Literature

Back cover

Cover

DOI: 10.1039/C4GC90038C

A general and direct synthesis of imidazolium ionic liquids using orthoesters

Do Joong Kim, Kyung Hwan Oh, Jin Kyoon Park

2014-07-22 Communication

DOI: 10.1039/C4GC00684D

Towards the rational biosynthesis of substituted phenazines and phenoxazinones by laccases

M. Conceição Oliveira, Lígia O. Martins

2014-06-06 Paper

DOI: 10.1039/C4GC00901K

Cobalt catalysts: very efficient for hydrogenation of biomass-derived ethyl levulinate to gamma-valerolactone under mild conditions

Huacong Zhou, Jinliang Song, Honglei Fan, Binbin Zhang, Yingying Yang, Jiayin Hu, Qinggong Zhu, Buxing Han

2014-06-05 Paper

DOI: 10.1039/C4GC00482E

Hydrothermal saline promoted grafting: a route to sulfonic acid SBA-15 silica with ultra-high acid site loading for biodiesel synthesis

C. Pirez, A. F. Lee, J. C. Manayil, C. M. A. Parlett, K. Wilson

2014-07-24 Communication

DOI: 10.1039/C4GC01139B

An aza-Michael addition protocol to fluoroalkylated β-amino acid derivatives and enantiopure trifluoromethylated N-heterocycles

Xing Yang, Zhuo Chen, Yuan Cai, Yi-Yong Huang, Norio Shibata

2014-08-15 Communication

DOI: 10.1039/C4GC01357C

High-yield production of levulinic acid from cellulose and its upgrading to γ-valerolactone

Daqian Ding, Jianjian Wang, Jinxu Xi, Xiaohui Liu, Guanzhong Lu, Yanqin Wang

2014-06-19 Paper

DOI: 10.1039/C4GC00737A

Enzymatic synthesis of ionic responsive lignin nanofibres through surface poly(N-isopropylacrylamide) immobilization

Guangzheng Gao, Muzaffer A. Karaaslan, John F. Kadla, Frank Ko

2014-06-23 Paper

DOI: 10.1039/C4GC00757C

You might also like

Compound Q&A

How should 2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) be stored?

2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) should be stored in ...

615-45-22-Methylbenzene-1,4-...
Compound Q&A

Is (1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide (CAS: 132747-20-7) safe?

(1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide is generally considered sa...

132747-20-7(1S,4S)-2,5-Diazabic...
Compound Q&A

What industries use (6-Chloropyridazin-3-YL)methanamine (CAS: 871826-15-2)?

(6-Chloropyridazin-3-YL)methanamine finds applications in the pharmaceutical ind...

871826-15-2(6-Chloropyridazin-3...
Compound Q&A

What are the main uses of 2-Fluoro-3-methylphenol (CAS: 77772-72-6)?

2-Fluoro-3-methylphenol is primarily used in the synthesis of pharmaceuticals, p...

77772-72-62-Fluoro-3-methylphe...
Compound Q&A

What precautions should be taken when handling 3-Methoxy-4-nitrobenzonitrile (CAS: 177476-75-4)?

When handling 3-Methoxy-4-nitrobenzonitrile, it is important to wear appropriate...

177476-75-43-Methoxy-4-nitroben...
Compound Q&A

What precautions should be taken when handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4)?

When handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4), it is ...

211949-57-4[1,3]Oxazolo[4,5-b]p...
Compound Q&A

What regulatory guidelines apply to 4-Ethynylbenzamide (CAS: 90347-86-7)?

4-Ethynylbenzamide (CAS: 90347-86-7) falls under various regulatory guidelines i...

90347-86-74-Ethynylbenzamide
Compound Q&A

What are the main uses of 3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone (CAS: 186822-57-1)?

3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone is primarily used as an intermediat...

186822-57-13-(2-Ethylphenyl)-2-...
Compound Q&A

What is (2-Fluoro-6-methoxyphenyl)acetic acid (CAS: 500912-19-6)?

(2-Fluoro-6-methoxyphenyl)acetic acid, also known as 4-fluoro-3-methoxybenzoic a...

500912-19-6(2-Fluoro-6-methoxyp...
Compound Q&A

What is the market or research trend for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9)?

Market trends for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9) indicat...

102196-18-92-[4-(Hydroxymethyl)...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.