The first rare earth organometallic complex of 1,4,7-trithiacyclononane: a precursor to unique cationic ethylene and α-olefin polymerisation catalysts supported by an all-sulfur donor ligand
Literature Information
Cara S. Tredget, Fanny Bonnet, Andrew R. Cowley, Philip Mountford
[Sc([9]aneS3)(CH2SiMe3)3], the first rare earth organometallic complex of 1,4,7-trithiacyclonane, is a precursor to ethylene and α-olefin polymerisation catalysts upon activation with BArF3 or [CPh3][BArF4] (ArF = C6F5); these are the first cationic rare earth organometallic catalysts supported by an all-sulfur donor ligand.
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