Mono- and digallane complexes of a tridentate amido-diamine ligand

Literature Information

Publication Date 2005-06-09
DOI 10.1039/B503705K
Impact Factor 6.222
Authors

Bing Luo, Benjamin E. Kucera, Wayne L. Gladfelter


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Abstract

Bis(2-dimethylaminoethyl)amido gallane, H2GaN(CH2CH2NMe2)2, that melts at 27 째C and remains stable upon heating at 55 째C for two days, was synthesized either from the reaction of the quinuclidine adduct of monochlorogallane with the lithium salt of the corresponding amine, or from the reaction of trimethylamine gallane and the amine; the latter affords an unusual co-product with both GaH2 and GaH3 bonded to the same amido nitrogen.

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