Homoleptic uranium(iii) imidodiphosphinochalcogenides including the first structurally characterised molecular trivalent actinide–Se bond

Literature Information

Publication Date 2005-05-18
DOI 10.1039/B503106K
Impact Factor 6.222
Authors

Andrew J. Gaunt, Brian L. Scott, Mary P. Neu


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Abstract

Preparation of U[N(EPPh2)2]3 (E = S or Se) by treating U[N(SiMe3)2]3 with three equivalents of NH(EPPh2)2 is described together with presentation of a hitherto unreported molecular crystal structure containing An(III)–Se bonds (An = actinide).

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