Interpenetrated networks from a novel nanometer-sized pseudopeptidic ligand, bridging water, and transition metal ions with cds topology

Literature Information

Publication Date 2005-06-21
DOI 10.1039/B502788H
Impact Factor 6.222
Authors

Luigi Casella, Nick Hadjiliadis, Enrico Monzani, Nikolaos Kourkoumelis, John C. Plakatouras


View Original

Abstract

The combination of a new pseudopeptidic ligand, transition metal ions, and bridging water molecules results in the formation of [M(μ-TBG)(μ-H2O)(H2O)2]·2H2O (M: Cu, Co and H2TBG: terephthaloylbisglycine); both compounds show rare two-fold interpenetrated three-dimensional cds-nets and reversible loss of coordinated and lattice water molecules.

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