Side-hole to anti-hole conversion in time-resolved transient spectral hole-burning of emerald: ground state level versus excited state population storage in low magnetic fields

Literature Information

Publication Date 2005-06-09
DOI 10.1039/B502079D
Impact Factor 3.676
Authors

Brendan F. Hayward, Hans Riesen


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Abstract

Time-resolved transient spectral hole-burning experiments in zero field and in low magnetic fields B∥c are reported for the chromium(III) R1-line, 2Ā(2E) ← 2Ā(4A2) of Chatham lab created emerald, Be3Al2Si6O18 ∶ Cr(III) (0.0017% per weight), in the temperature range of 3 to 12 K. In low magnetic fields and temperatures >5 K conversion of side-holes to anti-holes is observed with progressing time. Anti-holes are due to the population stored in ground state levels. The dynamics of the hole pattern can be well modelled by a set of coupled differential equations for the levels of the 4A2 and 2E multiplets. The measurements allow the simultaneous determination of g-factors and spin–lattice relaxation rates in the excited state and the ground state. At 6 K the relaxation times between the split ±1/2 2Ā(2E) excited state levels and ±3/2 2Ā(4A2) levels of the ground state are about 0.16 ms and 9 ms, respectively. From the temperature dependence it follows that the spin–lattice relaxation rates are dominated by Orbach processes in the experimental temperature range.

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