Cp*(iPr3P)Ru(Cl)(η2-HSiClMe2): the first complex with simultaneous Si–H and RuCl⋯SiCl inter-ligand interactions

Literature Information

Publication Date 2005-05-27
DOI 10.1039/B500679A
Impact Factor 6.222
Authors

Alexander L. Osipov, Sergei F. Vyboishchikov, Konstantin Y. Dorogov, Lyudmila G. Kuzmina, Judith A. K. Howard, Dmitrii A. Lemenovskii, Georgii I. Nikonov


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Abstract

The addition of HSiMe2Cl to the unsaturated compound Cp*(iPr3P)RuCl gives an unstable adduct which, according to NMR (JH–Si = 33.5 Hz), X-ray crystal structure and DFT evidence, is a silane σ-complex Cp*(iPr3P)Ru(Cl)(η2-HSiMe2Cl) supported by an unprecedented, simultaneous inter-ligand RuCl⋯SiCl hypervalent interaction between the chloride ligand on ruthenium and the SiMe2Cl group.

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