Cp*(iPr3P)Ru(Cl)(η2-HSiClMe2): the first complex with simultaneous Si–H and RuCl⋯SiCl inter-ligand interactions
Literature Information
Alexander L. Osipov, Sergei F. Vyboishchikov, Konstantin Y. Dorogov, Lyudmila G. Kuzmina, Judith A. K. Howard, Dmitrii A. Lemenovskii, Georgii I. Nikonov
The addition of HSiMe2Cl to the unsaturated compound Cp*(iPr3P)RuCl gives an unstable adduct which, according to NMR (JH–Si = 33.5 Hz), X-ray crystal structure and DFT evidence, is a silane σ-complex Cp*(iPr3P)Ru(Cl)(η2-HSiMe2Cl) supported by an unprecedented, simultaneous inter-ligand RuCl⋯SiCl hypervalent interaction between the chloride ligand on ruthenium and the SiMe2Cl group.
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