Formation of novel anionic gold–tin cluster compounds
Literature Information
Siegbert Hagen, Lars Wesemann, Ingo Pantenburg
A straightforward procedure for the formation of mixed metal Au/Sn clusters is presented: reaction of the heteroborate [SnB11H11]2− with phosphine gold electrophiles gave the clusters [Bu3NH]3[{(Et3P)Au(SnB11H11)}3] and [Bu3MeN]4[{(dppm)Au2(SnB11H11)2}2], which were characterised by X-ray diffraction.
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Chemical Communications

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