Formation of novel anionic gold–tin cluster compounds

Literature Information

Publication Date 2005-01-04
DOI 10.1039/B416472E
Impact Factor 6.222
Authors

Siegbert Hagen, Lars Wesemann, Ingo Pantenburg


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Abstract

A straightforward procedure for the formation of mixed metal Au/Sn clusters is presented: reaction of the heteroborate [SnB11H11]2− with phosphine gold electrophiles gave the clusters [Bu3NH]3[{(Et3P)Au(SnB11H11)}3] and [Bu3MeN]4[{(dppm)Au2(SnB11H11)2}2], which were characterised by X-ray diffraction.

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Chemical Communications

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