Meridional bicyclometalation with iron: a novel way of forming dianionic [C,N,C]-ligands
Literature Information
Ulrich Flörke
Bicyclometalation of aromatic substrates containing imine anchoring groups is achieved with a dimethyliron complex at −70 °C; azadiene systems undergo a regiospecific activation of 1,4-CH/N interchanged C–H bonds which may be aromatic or vinylic.
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