Pyramidalization of Gd3N inside a C80 cage. The synthesis and structure of Gd3N@C80

Literature Information

Publication Date 2004-11-16
DOI 10.1039/B412338G
Impact Factor 6.222
Authors

Steven Stevenson, J. Paige Phillips, Jon E. Reid, Marilyn M. Olmstead, Sankar Prasad Rath, Alan L. Balch


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Abstract

The X-ray crystal structure of Gd3N@C80•NiII(OEP)•1.5(benzene) shows that the Gd3N unit within the Ih C80 cage is pyramidal, whereas Sc3N@C80, Sc3N@C78, Sc3N@C68, Lu3N@C80 and Sc2ErN@C80 have planar M3N units.

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