Tetraarylethylene having two nitroxide groups: redox-switching of through-bond magnetic interaction by conformation change

Literature Information

Publication Date 2004-11-29
DOI 10.1039/B410858B
Impact Factor 6.222
Authors

Akihiro Ito, Yoshiaki Nakano, Tatsuhisa Kato, Kazuyoshi Tanaka


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Abstract

Reversible redox-switching of through-bond magnetic interaction has been achieved by conformation change of the tetraarylethylene moiety upon redox input: intramolecular magnetic interaction between two nitroxide groups is dead after oxidation, whereas it was alive before.

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