The substituent-dependent base-treatment chemistry of (η5-C5H5)Fe(CO)2SiR2SiR2Cl: formation of 1,2-disila-3-metallacyclobutanes, their ring-opened polymers, migrations and substitutions
Literature Information
Hemant K. Sharma, Keith H. Pannell
We report the formation of disilametallacycles, high molecular weight polymers or simple substitution products from the reactions of 1-(cyclopentadienyliron dicarbonyl)-2-chlorodisilanes with bases, LDA or n-BuLi.
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![Disodium (6R,7R)-7-{[(2R)-2-hydroxy-2-phenylacetyl]amino}-8-oxo-3-({[1-(sulfonatomethyl)-1H-tetrazol-5-yl]sulfanyl}methyl)-5-thia-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylate structure Disodium (6R,7R)-7-{[(2R)-2-hydroxy-2-phenylacetyl]amino}-8-oxo-3-({[1-(sulfonatomethyl)-1H-tetrazol-5-yl]sulfanyl}methyl)-5-thia-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylate structure](https://static.chemtradehub.com/structs/612/61270-78-8-6b58.webp)



![[4-(Hydroxymethyl)phenyl]acetic acid structure [4-(Hydroxymethyl)phenyl]acetic acid structure](https://static.chemtradehub.com/structs/734/73401-74-8-5a54.webp)