The first samarium(ii)-mediated aryl radical cyclisation onto an aromatic ring
Literature Information
Hiroaki Ohno, Hiroki Iwasaki, Toru Eguchi, Tetsuaki Tanaka
Intramolecular arylation of aryl radicals was mediated by SmI2/HMPA in the presence of i-PrOH to give spirocycles and/or reduced cine-cyclised products, while the reaction in the absence of i-PrOH gave the rearomatised fused rings.
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