Cu(0)-mediated living radical polymerisation in dimethyl lactamide (DML); an unusual green solvent with limited environmental impact
Literature Information
Publication Date
2015-10-08
DOI
10.1039/C5PY01420D
Impact Factor
5.582
Authors
Olivier Bertrand, Paul Wilson, James A. Burns, Gordon A. Bell, David M. Haddleton
View Original
Abstract
The synthesis of poly-acrylates, methacrylates and styrene derivatives by SET-LRP is reported in a user and environmentally friendly “green” solvent, dimethyl lactamide (DML). The occurrence of a SET-LRP mechanism in DML was demonstrated via UV-Vis spectroscopy measurements following the disproportionation of Cu(I) in the presence of N-containing ligands. The synthesis of hydrophobic and hydrophilic poly acrylate and methacrylate (methyl, n-butyl, lauryl, poly(ethylene glycol), 2-hydroxyethyl and 2-(dimethyamino)ethyl derivatives) and styrene was investigated. The controlled behaviour of the polymerisation was observed via kinetic experiments. Finally the possibility to produced well-defined polymers with functional chain-ends was demonstrated with the SET-LRP of poly(ethylene glycol) methyl ether acrylate.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
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Recommended Compounds
![1,1',1'',1'''-[Disulfanediylbis(carbonothioylnitrilo)]tetraethane structure](https://static.chemtradehub.com/structs/97-/97-77-8-f3e4.webp "1,1',1'',1'''-[Disulfanediylbis(carbonothioylnitrilo)]tetraethane structure")
1,1',1'',1'''-[Disulfanediylbis(carbonothioylnitrilo)]tetraethane
CAS Number:
97-77-8
Molecular Formula:
C10H20N2S4
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