Structurally diverse Rh(i) and Mn(i) complexes derived from the new ambidentate indeneligand, (1-{iPr2P(S)}-2-{NMe2})C9H6

Literature Information

Publication Date 2004-09-21
DOI 10.1039/B410328A
Impact Factor 6.222
Authors

Dominik Wechsler, Robert McDonald, Michael J. Ferguson, Mark Stradiotto


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Abstract

A new indene-based ligand featuring pendant phosphine sulfide and amine donor fragments has been developed; Rh(I) coordinates to the neutral form of the ligand in a κ2-[N,S] fashion, while the anionic form of the ligand binds Rh(I) and Mn(I) in κ2-[C,S] and η5 modes, respectively.

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