New high-nuclearity Ni–Pt carbonyl clusters: synthesis and X-ray structure of the ordered [HNi24Pt17(CO)46]5− and the substitutionally Ni/Pt disordered [Ni32Pt24(CO)56]6− cluster anions

Literature Information

Publication Date 2004-09-07
DOI 10.1039/B409522G
Impact Factor 6.222
Authors

Cristina Femoni, M. Carmela Iapalucci, Giuliano Longoni, Per H. Svensson


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Abstract

Condensation between preformed Ni–Pt and Pt carbonyl clusters leads to the new [H6−nNi24Pt17(CO)46]n− (n = 5, 6) and the substitutionally Ni/Pt disordered [Ni24(Ni12−xPtx)Pt20(CO)56]6− (x = 4) carbonyl clusters, the latter of which represents the highest nuclearity homoleptic carbonyl cluster anion so far reported.

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