Phenylthiolate as a σ- and π- donor ligand: synthesis of a 3-D organometallic coordination polymer [K2Fe(SPh)4]n

Literature Information

Publication Date 2004-05-24
DOI 10.1039/B404443F
Impact Factor 6.222
Authors

Xiao-Yan Yu, Lin-Hong Weng


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Abstract

The synthesis and crystal structure of the first mixed-metal organometallic polymer network containing phenylthiolato ligands, [K2Fe(SPh)4]n, are investigated. The simple phenylthiolate acts as a σ- and π-donor ligand to give a 3-D potassium iron coordination polymer with both metal–carbon and metal–sulfur coordination interactions.

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