Supertetrahedral decametallic Ni(ii) clusters directed by μ6-tris-alkoxides
Literature Information
Rachel Shaw, Ian S. Tidmarsh, Rebecca H. Laye, Barbara Breeze, Madeleine Helliwell, Euan K. Brechin, Sarah L. Heath, Mark Murrie, Stefan Ochsenbein, Hans-Ulrich Güdel, Eric J. L. McInnes
We report the syntheses, structures and magnetic properties of two decametallic Ni(II) clusters with unprecedented supertetrahedral cores, stabilised by the (hitherto unobserved) μ6-coordination modes of the tris-alkoxides {MeC(CH2O)3}3− and {C6H9O3}3−.
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