Ferromagnetic NiII–GdIII interactions in complexes with NiGd, NiGdNi, and NiGdGdNi cores supported by tripodal ligands

Literature Information

Publication Date 2004-04-05
DOI 10.1039/B401033G
Impact Factor 6.222
Authors

Tomoka Yamaguchi, Yukinari Sunatsuki, Masaaki Kojima, Haruo Akashi, Masanobu Tsuchimoto, Nazzareno Re, Shutaro Osa, Naohide Matsumoto


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Abstract

Dinuclear [(NiL)Gd(hfac)2(EtOH)] (H3L = 1,1,1-tris(N-salicylideneaminomethyl)ethane, Hhfac = hexafluoroacetylacetone), trinuclear [(NiL)2Gd(NO3)], and tetranuclear [(NiL)Gd(CH3CO2)2(MeOH)]2 complexes, were prepared by treating [Ni(HL)] with [Gd(hfac)3(H2O)2], Gd(NO3)3·6H2O, and Gd(CH3CO2)3·4H2O, respectively, in the presence of Et3N. All the complexes show that ferromagnetic interactions occur between the NiII and GdIII ions.

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