Ferromagnetic NiII–GdIII interactions in complexes with NiGd, NiGdNi, and NiGdGdNi cores supported by tripodal ligands
Literature Information
Tomoka Yamaguchi, Yukinari Sunatsuki, Masaaki Kojima, Haruo Akashi, Masanobu Tsuchimoto, Nazzareno Re, Shutaro Osa, Naohide Matsumoto
Dinuclear [(NiL)Gd(hfac)2(EtOH)] (H3L = 1,1,1-tris(N-salicylideneaminomethyl)ethane, Hhfac = hexafluoroacetylacetone), trinuclear [(NiL)2Gd(NO3)], and tetranuclear [(NiL)Gd(CH3CO2)2(MeOH)]2 complexes, were prepared by treating [Ni(HL)] with [Gd(hfac)3(H2O)2], Gd(NO3)3·6H2O, and Gd(CH3CO2)3·4H2O, respectively, in the presence of Et3N. All the complexes show that ferromagnetic interactions occur between the NiII and GdIII ions.
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