Synthesis of the stable UO2I2, the last of the uranyl dihalides. X-Ray crystal structure of [UO2I2(py)3]
Literature Information
Jean-Claude Berthet, Martine Nierlich, Michel Ephritikhine
Treatment of UO2(OTf)2 with pure Me3SiI led to the quantitative formation of UO2I2 (1). This compound dissolved in pyridine and thf to give the red adducts [UO2I2L3] {L = py (2) or thf (3)}, which were also obtained from the metathetical reaction of UO2(OTf)2 and KI. The crystal structure of 2 has been determined. The uranyl diiodide complexes 1–3 are thermally quite stable, providing that strictly anhydrous conditions are employed.
Related Literature
Effects of kinetic and transport phenomena on thermal explosion and oscillatory behaviour in a spherical reactor with mixed convection
Filipa Gonçalves de Azevedo, John F. Griffiths, Silvana S. S. Cardoso
DOI: 10.1039/C4CP02990A
Remarkable changes in the photoluminescent properties of Y2Ce2O7:Eu3+ red phosphors through modification of the cerium oxidation states and oxygen vacancy ordering
Athira K. V. Raj, P. Prabhakar Rao, T. S. Sreena, S. Sameera, Vineetha James, U. A. Renju
DOI: 10.1039/C4CP03311F
High thermal sensitivity and the selectable upconversion color of Ln, Yb:Y6O5F8 nanotubes
Carlos Zaldo, Concepción Cascales
DOI: 10.1039/C4CP03616F
Peculiar surface–interface properties of nanocrystalline ceria–cobalt oxides with enhanced oxygen storage capacity
Nan Qiu, Jing Zhang
DOI: 10.1039/C4CP03390F
Near room temperature reduction of graphene oxide Langmuir–Blodgett monolayers by hydrogen plasma
Gulbagh Singh, V. Divakar Botcha, D. S. Sutar, Pavan K. Narayanam, S. S. Talwar, R. S. Srinivasa, S. S. Major
DOI: 10.1039/C4CP00875H
On the dual character of charged metal–molecule hybrids and the opposite behaviour of the forward and reverse CT processes
J. Roman-Perez, S. P. Centeno, M. R. López-Ramírez, J. F. Arenas, J. Soto, I. López-Tocón, J. C. Otero
DOI: 10.1039/C4CP03984J
Probing molecular interaction in ionic liquids by low frequency spectroscopy: Coulomb energy, hydrogen bonding and dispersion forces
Koichi Fumino, Sebastian Reimann
DOI: 10.1039/C4CP01476F
Entropy reduction in unfolded peptides (and proteins) due to conformational preferences of amino acid residues
Reinhard Schweitzer-Stenner, Siobhan E. Toal
DOI: 10.1039/C4CP02108H
Probing the kinetic energy-release dynamics of H-atom products from the gas-phase reaction of O(3P) with vinyl radical C2H3
Su-Chan Jang, Jong-Ho Choi
DOI: 10.1039/C4CP03046J
You might also like
What is the market or research trend for N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0)?
N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0) is increasingly being used ...
What precautions should be taken when handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate (CAS: 1050507-06-6)?
When handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate, appropriate p...
What regulatory guidelines apply to diethyldiselane (CAS: 628-39-7)?
Diethyldiselane (CAS: 628-39-7) is classified under the Globally Harmonized Syst...
What is the market or research trend for oxocopper (CAS: 12053-18-8)?
The market for oxocopper (CAS: 12053-18-8) is primarily driven by its use in cat...
What is the market or research trend for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-carboxylic acid?
The market for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-c...
What is 2-(1-Pyrrolidinyl)-4-pyridinamine (CAS: 35981-63-6)?
2-(1-Pyrrolidinyl)-4-pyridinamine is a chemical compound with the CAS number 359...
What are the physical and chemical properties of 2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1)?
2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1) is a crystalline sol...
How is (S)-Alpha-allyl-proline hydrochloride (CAS: 129704-91-2) typically synthesized?
(S)-Alpha-allyl-proline hydrochloride is usually synthesized via a Wittig reacti...
What is 3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5)?
3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5) is an organic compound w...
How is Lys-SMCC-DM1 (CAS: 1281816-04-3) typically synthesized?
Lys-SMCC-DM1 is synthesized via a multi-step process involving the coupling of S...
Source Journal
Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry











![1-oxaspiro[4.4]nonan-6-one structure 1-oxaspiro[4.4]nonan-6-one structure](https://static.chemtradehub.com/structs/134/134179-01-4-e051.webp)


![N-{15-[(2,5-Dioxo-1-pyrrolidinyl)oxy]-15-oxo-3,6,9,12-tetraoxapentadec-1-yl}-2-(2-propyn-1-yloxy)acetamide structure N-{15-[(2,5-Dioxo-1-pyrrolidinyl)oxy]-15-oxo-3,6,9,12-tetraoxapentadec-1-yl}-2-(2-propyn-1-yloxy)acetamide structure](https://static.chemtradehub.com/structs/210/2101206-92-0-2eb5.webp)