Synthesis of the stable UO2I2, the last of the uranyl dihalides. X-Ray crystal structure of [UO2I2(py)3]
Literature Information
Publication Date
2004-02-27
DOI
10.1039/B400717D
Impact Factor
6.222
Authors
Jean-Claude Berthet, Martine Nierlich, Michel Ephritikhine
View Original
Abstract
Treatment of UO2(OTf)2 with pure Me3SiI led to the quantitative formation of UO2I2 (1). This compound dissolved in pyridine and thf to give the red adducts [UO2I2L3] {L = py (2) or thf (3)}, which were also obtained from the metathetical reaction of UO2(OTf)2 and KI. The crystal structure of 2 has been determined. The uranyl diiodide complexes 1–3 are thermally quite stable, providing that strictly anhydrous conditions are employed.
Recommended Journals
European Journal of Wood and Wood Products
Science Progress
Fibre Chemistry
Proceedings of the National Academy of Sciences of the United States of America
Israel Journal of Chemistry
Journal of Catalysis
Pharmacological Reviews
Journal of Physics and Chemistry of Solids
Molecular Pharmacology
Pure and Applied Chemistry
Related Literature
Estimates of internal energies of vaporisation of some room temperature ionic liquids
Konrad Swiderski, Andrew McLean, Charles M. Gordon, D. Huw Vaughan
2004-09-07
Communication
DOI: 10.1039/B408334B
Mono- and bis(tetrathiafulvaleno)hexadehydro[12]annulenes
Kenji Hara, Masashi Hasegawa, Yoshiyuki Kuwatani, Hideo Enozawa, Masahiko Iyoda
2004-08-13
Communication
DOI: 10.1039/B407200F
A new organic superconductor β-(meso-DMBEDT-TTF)2PF6
Tadashi Kawamoto, Takehiko Mori, Hiroshi Moriyama, Yutaka Nishio, Koji Kajita
2004-09-21
Communication
DOI: 10.1039/B409631B
The anion sequence in the phase transformation of mesostructures templated by non-ionic block copolymers
Jiawei Tang, Chengzhong Yu, Xufeng Zhou, Xiaoxia Yan, Dongyuan Zhao
2004-08-25
Communication
DOI: 10.1039/B408100E
A modular ditopic crown-shielded phosphate ion-pair receptor
Patrick Gunning, Andrew C. Benniston, Robert D. Peacock
2004-08-20
Communication
DOI: 10.1039/B409132A
A new approach to bioconjugates for proteins and peptides (“pegylation”) utilising living radical polymerisation
François Lecolley, Lei Tao, Giuseppe Mantovani, Ian Durkin, Sylvie Lautru, David M. Haddleton
2004-07-28
Communication
DOI: 10.1039/B407712A
Mechanism of hydrogen transfer to imines from a hydroxycyclopentadienyl ruthenium hydride. Support for a stepwise mechanism
Joseph S. M. Samec, Alida H. Éll, Jan-E. Bäckvall
2004-10-06
Communication
DOI: 10.1039/B410698A
Water reduction and oxidation on Pt–Ru/Y2Ta2O5N2catalyst under visible light irradiation
Meiying Liu, Wansheng You, Zhibin Lei, Guohua Zhou, Jianjun Yang, Guopeng Wu, Guijun Ma, Guoyou Luan, Tuyoshi Takata, Michikazu Hara, Can Li
2004-08-19
Communication
DOI: 10.1039/B407892F
Reversible folding/unfolding of linear molecular strands into helical channel-like complexes upon proton-modulated binding and release of metal ions
Adrian-Mihail Stadler, Nathalie Kyritsakas, Jean-Marie Lehn
2004-08-11
Communication
DOI: 10.1039/B407168A
Bis(diethylamino)carbene and the mechanism of dimerisation for simple diaminocarbenes
Roger W. Alder, Leila Chaker, François P. V. Paolini
2004-08-20
Communication
DOI: 10.1039/B409112D
You might also like
Compound Q&A
What is the market or research trend for N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0)?
N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0) is increasingly being used ...
52818-63-0N-(4-Methoxybenzyl)-...
Compound Q&A
What precautions should be taken when handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate (CAS: 1050507-06-6)?
When handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate, appropriate p...
1050507-06-6Ethyl 4-(2-chlorophe...
Compound Q&A
What regulatory guidelines apply to diethyldiselane (CAS: 628-39-7)?
Diethyldiselane (CAS: 628-39-7) is classified under the Globally Harmonized Syst...
628-39-7Diethyldiselane
Compound Q&A
What is the market or research trend for oxocopper (CAS: 12053-18-8)?
The market for oxocopper (CAS: 12053-18-8) is primarily driven by its use in cat...
12053-18-8oxocopper; oxo-(oxoc...
Compound Q&A
What is the market or research trend for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-carboxylic acid?
The market for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-c...
1268519-54-55-{[(2-Methyl-2-prop...
Compound Q&A
What is 2-(1-Pyrrolidinyl)-4-pyridinamine (CAS: 35981-63-6)?
2-(1-Pyrrolidinyl)-4-pyridinamine is a chemical compound with the CAS number 359...
35981-63-62-(1-Pyrrolidinyl)-4...
Compound Q&A
What are the physical and chemical properties of 2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1)?
2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1) is a crystalline sol...
91556-75-12-(3-Pyridinyl)-1-az...
Compound Q&A
How is (S)-Alpha-allyl-proline hydrochloride (CAS: 129704-91-2) typically synthesized?
(S)-Alpha-allyl-proline hydrochloride is usually synthesized via a Wittig reacti...
129704-91-2(S)-Alpha-allyl-prol...
Compound Q&A
What is 3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5)?
3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5) is an organic compound w...
4857-42-53-Methyl-1,2-oxazole...
Compound Q&A
How is Lys-SMCC-DM1 (CAS: 1281816-04-3) typically synthesized?
Lys-SMCC-DM1 is synthesized via a multi-step process involving the coupling of S...
1281816-04-3Lys-SMCC-DM1
Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry
Recommended Compounds
![1-{3-[4-Amino-3-(4-phenoxyphenyl)-1H-pyrazolo[3,4-d]pyrimidin-1-yl]-1-piperidinyl}-2,3-dihydroxy-1-propanone structure](https://static.chemtradehub.com/structs/122/1226872-27-0-e037.webp "1-{3-[4-Amino-3-(4-phenoxyphenyl)-1H-pyrazolo[3,4-d]pyrimidin-1-yl]-1-piperidinyl}-2,3-dihydroxy-1-propanone structure")
1-{3-[4-Amino-3-(4-phenoxyphenyl)-1H-pyrazolo[3,4-d]pyrimidin-1-yl]-1-piperidinyl}-2,3-dihydroxy-1-propanone
CAS Number:
1226872-27-0
Molecular Formula:
C25H26N6O4
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.