Bis(diethylamino)carbene and the mechanism of dimerisation for simple diaminocarbenes

Literature Information

Publication Date 2004-08-20
DOI 10.1039/B409112D
Impact Factor 6.222
Authors

Roger W. Alder, Leila Chaker, François P. V. Paolini


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Abstract

Bis(diethylamino)carbene is kinetically stable to dimerization in THF at ambient temperature; dimer formed during carbene generation arises from reaction of the carbene with the precursor formamidinium ion; this is probably the commonest route to tetraaminoethene dimers, and in a related case the intermediate protonated tetraaminoethene can be observed by NMR.

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