Bis(diethylamino)carbene and the mechanism of dimerisation for simple diaminocarbenes
Literature Information
Roger W. Alder, Leila Chaker, François P. V. Paolini
Bis(diethylamino)carbene is kinetically stable to dimerization in THF at ambient temperature; dimer formed during carbene generation arises from reaction of the carbene with the precursor formamidinium ion; this is probably the commonest route to tetraaminoethene dimers, and in a related case the intermediate protonated tetraaminoethene can be observed by NMR.
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