Simultaneous quantification of analytes in quaternary mixtures using dual pulse staircase voltammetry and genetically optimised neural networks
Literature Information
Publication Date
2004-03-17
DOI
10.1039/B400577P
Impact Factor
4.616
Authors
Edward Richards, Conrad Bessant, Selweyan Saini
View Original
Abstract
This paper describes the simultaneous quantification of four aliphatic compounds (ethanol, methanol, fructose and glucose) mixed in varying concentrations. The method used employs dual pulse staircase voltammetry (DPSV) to acquire an electrochemical voltammogram from the mixture. An artificial neural network, optimised using an elitist genetic algorithm, is then used to determine the concentration of each individual analyte from the voltammogram. The best average RMS errors achieved when testing with unseen data were 5.03%, 7.72%, 3.29% and 4.00% for maximum analyte concentrations of ethanol, methanol, fructose and glucose respectively. This work represents an important step forward because DPSV data is notoriously difficult to calibrate due to complex electrode–analyte interactions, and had not previous been shown to be amenable to quaternary mixtures.
Related Literature
Tailoring the supramolecular interaction of ionic liquids for high-sensitivity temperature monitoring under high pressure
Beihang Xu, Yao An, Xinjia Zheng, Zhiwu Chen, Zhaoxiang Yang, Yongjia Yang, An Zhang, Yapei Wang, Yonglin He
2023-11-17
Paper
DOI: 10.1039/D3TA05615E
Spiro[fluorene-9,9′-xanthene]-based hole shuttle materials for effective defect passivation in perovskite solar cells
Bommaramoni Yadagiri, Sanjay Sandhu, Ashok Kumar Kaliamurthy, Francis Kwaku Asiam, Jongdeok Park, Appiagyei Ewusi Mensah, Jae-Joon Lee
2023-11-21
Paper
DOI: 10.1039/D3TA05915D
Solvation structure regulation of an organic small molecule additive for dendrite-free aqueous zinc-ion batteries
Xiaomin Li, Jinwei Miao, Fulong Hu, Kang Yan, Lin Song, Huiqing Fan, Longtao Ma, Weijia Wang
2023-11-27
Paper
DOI: 10.1039/D3TA05814J
Aromatic polyaroxydiazole pseudocapacitive anode materials with tunable electrochemical performance through side group engineering
2023-11-27
Paper
DOI: 10.1039/D3TA06374G
Correction: Achieving highly efficient CO2 to CO electroreduction exceeding 300 mA cm−2 with single-atom nickel electrocatalysts
Hui-Yun Jeong, Mani Balamurugan, Eun-suk Jeong, Uk Sim
2023-12-06
Correction
DOI: 10.1039/D3TA90261G
Counterion chemistry of 5-halo (X: Cl, Br, I)-uracil derived carbon nitride: unlocking enhanced photocatalytic performance
Toshali Bhoyar, B. Moses Abraham, Akanksha Gupta, Dong Jin Kim, Nilesh R. Manwar, Kedhareswara Sairam Pasupuleti, Suresh S. Umare
2023-12-02
Paper
DOI: 10.1039/D3TA04938H
Low band gap semiconducting covalent organic framework films with enhanced photocatalytic hydrogen evolution
Hüseyin Küçükkeçeci, Rajendra Prasad Paitandi, Vincent Weigelt, Veit Dippold, Shu Seki, Arne Thomas
2023-11-20
Paper
DOI: 10.1039/D3TA04552H
Utilizing the synergistic effect between the Schottky barrier and field redistribution to achieve high-density, low-consumption, cellulose-based flexible dielectric films for next-generation green energy storage capacitors
Hansong Wei, Shibo Zhao, Qing Guo, Yuhan Bai, Siting Wang, Peiyao Sun, Kang Du, Yating Ning, Ye Tian, Xiaohua Zhang, Hongmei Jing, Yongping Pu, Sufeng Zhang
2023-11-20
Paper
DOI: 10.1039/D3TA05975H
Looking back at the 10th anniversary year of Journal of Materials Chemistry A, B and C
Jeroen Cornelissen, Natalie Stingelin
2023-12-11
Editorial
DOI: 10.1039/D3TA90260A
You might also like
Compound Q&A
How should waste containing 2-Ethyl-4-Methyl-1H-Imidazole-5-Carbaldehyde (CAS: 88634-80-4) be handled?
Waste containing 2-Ethyl-4-Methyl-1H-Imidazole-5-Carbaldehyde (CAS: 88634-80-4) ...
88634-80-42-Ethyl-4-Methyl-1H-...
Compound Q&A
What industries use Triethoxy(octyl)silane (CAS: 1385031-14-0)?
Triethoxy(octyl)silane (CAS: 1385031-14-0) is widely used in the pharmaceuticals...
1385031-14-0Triethoxy(octyl)sila...
Compound Q&A
Are there alternatives to 3-iodo-7-nitro-1H-indazole (CAS: 864724-64-1) in synthesis?
Several alternatives to 3-iodo-7-nitro-1H-indazole (CAS: 864724-64-1) exist in t...
864724-64-13-iodo-7-nitro-1H-in...
Compound Q&A
Are there alternatives to Benzene, bis[(trimethoxysilyl)ethyl] (CAS: 266317-71-9) in synthesis?
Yes, there are alternatives to Benzene, bis[(trimethoxysilyl)ethyl] (CAS: 266317...
266317-71-9Benzene, bis[(trimet...
Compound Q&A
Is Isothiazole-3-carbonitrile (CAS: 1452-17-1) safe?
Isothiazole-3-carbonitrile (CAS: 1452-17-1) is generally considered safe when us...
1452-17-1Isothiazole-3-carbon...
Compound Q&A
Is (3-Chlorophenyl)methanol (CAS: 873-63-2) safe?
(3-Chlorophenyl)methanol (CAS: 873-63-2) is considered low to moderately toxic. ...
873-63-2(3-Chlorophenyl)meth...
Compound Q&A
How is (2S,3S)-2-Hydroxy-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)-3-(2-naphthyl)propanoic acid (CAS: 959583-98-3) typically synthesized?
(2S,3S)-2-Hydroxy-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)-3-(2-naphthyl)pr...
959583-98-3(2S,3S)-2-Hydroxy-3-...
Compound Q&A
What precautions should be taken when handling Methyl 2-(bromomethyl)-5-methoxybenzoate (CAS: 788081-99-2)?
Proper handling of methyl 2-(bromomethyl)-5-methoxybenzoate requires the use of ...
788081-99-2Methyl 2-(bromomethy...
Compound Q&A
What is 6,8-Dibromoimidazo[1,2-a]pyridine-2-carboxylic acid (CAS: 904805-36-3)?
6,8-Dibromoimidazo[1,2-a]pyridine-2-carboxylic acid (CAS: 904805-36-3) is an aro...
904805-36-36,8-Dibromoimidazo[1...
Compound Q&A
Is 3-Amino-5-bromo-2-pyridinecarbonitrile (CAS: 573675-27-1) safe?
3-Amino-5-bromo-2-pyridinecarbonitrile is considered safe when handled under pro...
573675-27-13-Amino-5-bromo-2-py...
Source Journal
Analyst
CiteScore:
7.8
Self-citation Rate:
5.6%
Articles per Year:
653
Analyst publishes analytical and bioanalytical research that reports premier fundamental discoveries and inventions, and the applications of those discoveries, unconfined by traditional discipline barriers.
Recommended Compounds
methanone structure](https://static.chemtradehub.com/structs/814/81449-01-6-786d.webp "[4-(Hydroxymethyl)phenyl](phenyl)methanone structure")
![[3-Chloro-5-(diethylcarbamoyl)phenyl]boronic acid structure](https://static.chemtradehub.com/structs/957/957120-59-1-febc.webp "[3-Chloro-5-(diethylcarbamoyl)phenyl]boronic acid structure")
[3-Chloro-5-(diethylcarbamoyl)phenyl]boronic acid
CAS Number:
957120-59-1
Molecular Formula:
C11H15BClNO3
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.