The sum-rule relation among phenomenological transport coefficients and its consequences in the analysis of collective diffusion problems
Literature Information
In this paper, we discuss the sum-rule that relates the phenomenological coefficients in the multicomponent random alloy system in the case where the isolated vacancy mechanism is operating. We present applications of this sum-rule to intrinsic diffusion in multicomponent alloys, intrinsic diffusion in mixed alkali halides and demixing of multicomponent transition metal oxides in an oxygen potential gradient and an electric field. In each case, a very substantial simplification in the analysis is made possible because of the sum-rule.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.













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