A new (63)·(69.81) non-interpenetrated paramagnetic network with helical nanochannels based on a tricarboxylic perchlorotriphenylmethyl radical

Literature Information

Publication Date 2004-04-22
DOI 10.1039/B315147F
Impact Factor 6.222
Authors

Daniel Maspoch, Daniel Ruiz-Molina, Klaus Wurst, Concepció Rovira, Jaume Veciana


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Abstract

The reaction of a 3-connecting PTMTC radical and a 2-connecting 4,4′-bipyridine ligands with Co(MeCOO)2·4H2O forms a paramagnetic non-interpenetrated supramolecular network, Co(PTMTC)(4,4′-bpy)(H2O)3·6EtOH·2H2O (MOROF-2), with an unprecedented (63)·(69.81) topology exhibiting helical nanochannels.

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