Optical bands of dodecanuclear compounds H4PVMo11O40·yH2O with Keggin structure. Semiclassical vibronic model

Literature Information

Publication Date 2004-03-16
DOI 10.1039/B312753B
Impact Factor 3.676
Authors

S. Klokishner, J. Melsheimer, F. S. Jentoft, R. Schlögl


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Abstract

The problem of optical spectra of dodecanuclear clusters with the Keggin structure is considered. Charge-transfer and d–d-bands arising from intact and ill-defined species formed on different stages of disintegration of the heteropoly acid H4PVMo11O40·yH2O are investigated in detail. On the basis of the performed calculations the transformation of optical spectra of H4PVMo11O40·yH2O under increasing temperature and time on stream is explained.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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