In flagrante metallo-cyclophane self-assembly?
Literature Information
Peter J. Cragg, Fenton R. Heirtzler, Mark J. Howard, Ivan Prokes, Thomas Weyhermüller
The dimeric self-assembly of an alkyl-substituted pyrazine–pyridine hybrid ligand with copper(I) initially affords its sterically congested, C2-symmetric stereoisomer, which then undergoes partial isomerisation to a dynamic mixture containing the less crowded meso-configured diastereomer.
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