Preparation and electrochemical behaviour of hydrophobic vitamin B12 covalently immobilized onto platinum electrode
Literature Information
Hisashi Shimakoshi, Mami Tokunaga, Keita Kuroiwa, Nobuo Kimizuka, Yoshio Hisaeda
Hydrophobic vitamin B12 was covalently immobilized onto a platinum electrode surface, and the immobilized complex exhibits Co(II)/Co(I) redox couple and in situ the Co(I) species reacts with phenethyl bromide to form styrene under irradiation with visible light with a turnover number of over 6000 for 1 h.
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