A diatropic ring current in a fluorofullerene trannulene

Literature Information

Publication Date 2003-10-22
DOI 10.1039/B307514C
Impact Factor 6.222
Authors

Patrick W Fowler, Alessandro Soncini, John P B Sandall


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Abstract

Ipsocentric current-density maps for a fluorofullerene derivative, C60F15H3, modelling the addition pattern of the experimentally characterised C60F15[CBr(CO2Et)2]3 which contains an [18]trans-annulene system, reveal a diamagnetic ring current dominated by the contribution of the four HOMO electrons, as in a classical (4n + 2) aromatic annulene.

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