Mesoporous hybrid materials containing two transition metal ions, one in the framework, the other in the channel pores

Literature Information

Publication Date 2003-06-03
DOI 10.1039/B303492P
Impact Factor 6.222
Authors

Robert J. P. Corriu, Ahmad Mehdi, Catherine Reyé, Chloé Thieuleux


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Abstract

Mesoporous hybrid materials containing bridged metal–cyclam moieties in the silicate framework were synthesized by using triblock copolymer F127 as template and SiH3 as hydrolysable terminal groups; grafting of a metal–cyclam precursor in the channel pores led to materials containing two different strongly chelated transition metal ions in two steps.

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