![4,4-Difluoro-2-methyl-1-{[(2-methyl-2-propanyl)oxy]carbonyl}-L-proline structure](https://static.chemtradehub.com/structs/119/1194032-23-9-f426.webp "4,4-Difluoro-2-methyl-1-{[(2-methyl-2-propanyl)oxy]carbonyl}-L-proline structure")
4,4-Difluoro-2-methyl-1-{[(2-methyl-2-propanyl)oxy]carbonyl}-L-proline
CAS Number:
1194032-23-9
Molecular Formula:
C11H17F2NO4
Stabilisation of an ortho-deprotonated mesityl group within the unusual [{2,4,6-Me3C6H2P}{4,6-Me2C6H2(2-CH2)P}Sn]3− stannate ion
Literature Information
Publication Date
2003-05-21
DOI
10.1039/B303390M
Impact Factor
6.222
Authors
Mary McPartlin, Anthony D. Woods, Christopher M. Pask, Thomas Vogler, Dominic S. Wright
View Original
Abstract
The reaction of 2,4,6-Me3C6H2PHNa with Sn(NMe2)2 (3 : 1 equivalents, respectively) results in the formation of the unusual [{2,4,6-Me3C6H2P}{4,6-Me2C6H2(2-CH2)P}Sn]3− stannate trianion in the heterometallic cage [{2,4,6-Me3C6H2P}{4,6-Me2C6H2(2-CH2)P}Sn]Na3·2TMEDA]4 (1), in which unprecedented ortho-Me deprotonation of a [2,4,6-Me3C6H2P]2− ligand has occurred.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry
Recommended Compounds
5-Bromo-2-chloro-N-methoxy-N-methylisonicotinamide
CAS Number:
1256790-08-5
Molecular Formula:
C8H8BrClN2O2
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