Stabilisation of an ortho-deprotonated mesityl group within the unusual [{2,4,6-Me3C6H2P}{4,6-Me2C6H2(2-CH2)P}Sn]3− stannate ion
Literature Information
Mary McPartlin, Anthony D. Woods, Christopher M. Pask, Thomas Vogler, Dominic S. Wright
The reaction of 2,4,6-Me3C6H2PHNa with Sn(NMe2)2 (3 : 1 equivalents, respectively) results in the formation of the unusual [{2,4,6-Me3C6H2P}{4,6-Me2C6H2(2-CH2)P}Sn]3− stannate trianion in the heterometallic cage [{2,4,6-Me3C6H2P}{4,6-Me2C6H2(2-CH2)P}Sn]Na3·2TMEDA]4 (1), in which unprecedented ortho-Me deprotonation of a [2,4,6-Me3C6H2P]2− ligand has occurred.
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