Stabilisation of an ortho-deprotonated mesityl group within the unusual [{2,4,6-Me3C6H2P}{4,6-Me2C6H2(2-CH2)P}Sn]3− stannate ion

Literature Information

Publication Date 2003-05-21
DOI 10.1039/B303390M
Impact Factor 6.222
Authors

Mary McPartlin, Anthony D. Woods, Christopher M. Pask, Thomas Vogler, Dominic S. Wright


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Abstract

The reaction of 2,4,6-Me3C6H2PHNa with Sn(NMe2)2 (3 : 1 equivalents, respectively) results in the formation of the unusual [{2,4,6-Me3C6H2P}{4,6-Me2C6H2(2-CH2)P}Sn]3− stannate trianion in the heterometallic cage [{2,4,6-Me3C6H2P}{4,6-Me2C6H2(2-CH2)P}Sn]Na3·2TMEDA]4 (1), in which unprecedented ortho-Me deprotonation of a [2,4,6-Me3C6H2P]2− ligand has occurred.

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