Noncatalytic Heck coupling reaction using supercritical water
Literature Information
Rong Zhang, Masahiro Sato
Heck coupling of iodobenzene with styrene can be promoted in supercritical water without using catalyst, and the conversion reaches over 70% within 10 min in the presence of base, such as KOAc, in which case the yield of stilbene is 55.6% (both trans- and cis-stilbene).
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![4,4-Difluoro-2-methyl-1-{[(2-methyl-2-propanyl)oxy]carbonyl}-L-proline structure 4,4-Difluoro-2-methyl-1-{[(2-methyl-2-propanyl)oxy]carbonyl}-L-proline structure](https://static.chemtradehub.com/structs/119/1194032-23-9-f426.webp)


