Solid state structures of pentacoordinated λ3-iodanes with a trigonal bipyramidal geometry: synthesis of diphenyl- and alkynyl(phenyl)-λ3-iodane complexes with 1,10-phenanthroline

Literature Information

Publication Date 2003-05-16
DOI 10.1039/B302579A
Impact Factor 6.222
Authors

Masahito Ochiai, Takashi Suefuji, Kazunori Miyamoto, Motoo Shiro


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Abstract

The single crystal X-ray structure of the supramolecular complex formed between diphenyl-λ3-iodane (Ph2IBF4) or 1-alkynyl(phenyl)-λ3-iodane [ButCCI(Ph)BF4] and 1,10-phenanthroline indicates a hitherto unknown distorted trigonal bipyramidal geometry around iodine(III), in which 1,10-phenanthroline acts as a bidentate ligand and occupies equatorial sites.

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