IM-19: a new flexible microporous gallium based-MOF framework with pressure- and temperature-dependent openings
Literature Information
Gérald Chaplais, Angélique Simon-Masseron, Claude Lecomte, Delphine Bazer-Bachi, Nicolas Bats, Joël Patarin
Five metal–organic frameworks (MOFs) based on the same three-dimensional gallium terephthalate network (IM-19) are described, and an incommensurate structure (for the as-synthesized form) as well as two remarkable guest-free polymorphs (open and closed) are highlighted.
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