Insertion of organoindium carbenoids into rhodium halide bonds: revisiting a classic type of transition metal–group 13 metal bond formation

Literature Information

Publication Date 2003-03-31
DOI 10.1039/B301928D
Impact Factor 6.222
Authors

Tobias Steinke, Christian Gemel, Mirza Cokoja, Manuela Winter, Roland A. Fischer


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Abstract

Insertion of the carbenoid group 13 metal species InCp* (Cp* = pentamethylcyclopentadienyl) and InC(SiMe3)3 into the Rh–Cl bonds of [{RhCp*Cl2}2] yields the new complexes [Cp*Rh(InCp*)3(Cl)2] 1 and [Cp*Rh(μ2-Cl)2(InC(SiMe3)3)3] 2, respectively, exhibiting novel cage-like intermetallic complexes with In–Cl–In bridges.

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Chemical Communications

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ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

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