Tuning of ruthenium N-heterocyclic carbenecatalysts for ATRP
Literature Information
Lionel Delaude, Sébastien Delfosse, Aurore Richel, Albert Demonceau, Alfred F. Noels
Depending on the substituents, R1 and R2, ruthenium(II)–p-cymene complexes bearing N-heterocyclic carbene ligands are either efficient catalysts for the well-controlled atom transfer radical polymerisation of methyl methacrylate and styrene, or promote a redox-initiated free-radical process.
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