trans-4-(4-Morpholinyl)cyclohexanol hydrochloride (1:1)
CAS Number:
1588441-09-1
Molecular Formula:
C10H20ClNO2
Tandem double acylation/[3,3]-rearrangement of aliphatic nitro compounds: a route to α-oxygenated oxime derivatives
Literature Information
Publication Date
2019-05-29
DOI
10.1039/C9OB01005J
Impact Factor
3.876
Authors
Yulia V. Nelyubina, Alexey Yu. Sukhorukov, Sema L. Ioffe, Andrey A. Tabolin
View Original
Abstract
A new tandem double acylation/rearrangement reaction of nitro compounds is described. It has a broad substrate scope allowing the mild and efficient synthesis of α-acyloxy oxime esters in high yields and regioselectivity. According to the obtained data, the mechanism for transformation was proposed. The utility of the obtained α-hydroxy oxime esters was demonstrated.
Recommended Journals
Related Literature
Solid-state NMR as a probe of anion binding: molecular dynamics and associations in a [5]polynorbornane bisurea host complexed with terephthalate
Aditya Rawal, James M. Hook, Ryan N. Robson, Daniel Gunzelmann, Frederick M. Pfeffer, Luke A. O'Dell
2015-07-28
Paper
DOI: 10.1039/C5CP03628C
Energy and temperature dependence of rigid unit modes in AlPO4-5
Gordon J. Kearley, Yun Liu, Dehong Yu, Richard A. Mole, Chris D. Ling, Ray L. Withers
2015-07-17
Paper
DOI: 10.1039/C5CP01723H
Unusual Mn coordination and redox chemistry in the high capacity borate cathode Li7Mn(BO3)3
Christopher Eames, Stephen M. Wood, M. Saiful Islam
2015-07-29
Paper
DOI: 10.1039/C5CP02711J
Impact of the plasmonic near- and far-field resonance-energy shift on the enhancement of infrared vibrational signals
Jochen Vogt, Christian Huck, Andrea Toma
2014-12-08
Paper
DOI: 10.1039/C4CP04851B
Fundamental aspects in surface self-assembly: theoretical implications of molecular polarity and shape
Emilian Tuca, Irina Paci
2016-02-03
Paper
DOI: 10.1039/C5CP04479K
Strong electron donation induced differential nonradiative decay pathways for para and meta GFP chromophore analogues
Tanmay Chatterjee, Mrinal Mandal, Venkatesh Gude, Partha Pratim Bag, Prasun K. Mandal
2015-06-25
Paper
DOI: 10.1039/C5CP03086B
Soft X-ray absorption spectroscopy of Ar2 and ArNe dimers and small Ar clusters
Ghazal Jabbari, Tsveta Miteva, Vasili Stumpf, Kirill Gokhberg, Patrick O'Keeffe, Alessandra Ciavardini, Paola Bolognesi, Marcello Coreno, Lorenzo Avaldi, Elham Keshavarz, Maryam Ghandehari, Manijeh Tozihi, Carlo Callegari, Michele Alagia, Antti Kivimäki, Robert Richter
2015-07-22
Paper
DOI: 10.1039/C5CP03276H
Addition of low concentrations of an ionic liquid to a base oil reduces friction over multiple length scales: a combined nano- and macrotribology investigation
Hua Li, Anthony E. Somers, Patrick C. Howlett, Maria Forsyth, Rob Atkin
2016-02-05
Paper
DOI: 10.1039/C5CP07061A
Tuning the charge state of Ag and Au atoms and clusters deposited on oxide surfaces by doping: a DFT study of the adsorption properties of nitrogen- and niobium-doped TiO2 and ZrO2
Philomena Schlexer, Antonio Ruiz Puigdollers, Gianfranco Pacchioni
2015-07-31
Paper
DOI: 10.1039/C5CP03834K
Novel porphyrin-preparation, characterization, and applications in solar energy conversion
Jianfeng Lu, Hao Li, Shuangshuang Liu, Yu-Cheng Chang, Hui-Ping Wu, Eric Wei-Guang Diau, Mingkui Wang
2016-02-04
Paper
DOI: 10.1039/C5CP05658F
You might also like
Compound Q&A
What is 1-(2,4,6-Trifluorophenyl)ethanol (CAS: 1250113-83-7)?
1-(2,4,6-Trifluorophenyl)ethanol is an organic compound with the CAS number 1250...
1250113-83-71-(2,4,6-Trifluoroph...
Compound Q&A
Is 1-(2,4-Dimethoxybenzyl)-4-(hydroxymethyl)-2-pyrrolidinone (CAS: 919111-34-5) safe?
1-(2,4-Dimethoxybenzyl)-4-(hydroxymethyl)-2-pyrrolidinone (CAS: 919111-34-5) is ...
919111-34-51-(2,4-Dimethoxybenz...
Compound Q&A
What are the physical and chemical properties of (7S,15R)-6β,15-Diacetoxy-7α,20-epoxy-7-hydroxykaura-2,16-dien-1-one (CAS: 51419-51-3)?
(7S,15R)-6β,15-Diacetoxy-7α,20-epoxy-7-hydroxykaura-2,16-dien-1-one is a crystal...
51419-51-3(7S,15R)-6β,15-Diace...
Compound Q&A
What regulatory guidelines apply to rac-ethyl (1r,4r)-4-hydroxycyclohexane-1-carboxylate, trans (CAS: 3618-04-0)?
The compound rac-ethyl (1r,4r)-4-hydroxycyclohexane-1-carboxylate, trans (CAS: 3...
3618-04-0rac-ethyl (1r,4r)-4-...
Compound Q&A
What is the market or research trend for 2-(2,4-Difluorophenoxy)-3-nitropyridine (CAS: 175135-62-3)?
The market for 2-(2,4-Difluorophenoxy)-3-nitropyridine (CAS: 175135-62-3) is cur...
175135-62-32-(2,4-Difluoropheno...
Compound Q&A
What are the main uses of 6-Diazo-5-oxo-L-norleucine (CAS: 157-03-9)?
The main uses of 6-Diazo-5-oxo-L-norleucine (CAS: 157-03-9) include research in ...
157-03-96-Diazo-5-oxo-L-norl...
Compound Q&A
What precautions should be taken when handling 2-Aminoethyl-mono-amide-DOTA-tris(tBu ester) (CAS: 173308-19-5)?
When handling 2-Aminoethyl-mono-amide-DOTA-tris(tBu ester) (CAS: 173308-19-5), i...
173308-19-52-Aminoethyl-mono-am...
Compound Q&A
How is 5-Methylimidazo[1,2-a]pyridine-3-carbaldehyde (CAS: 178488-37-4) typically synthesized?
5-Methylimidazo[1,2-a]pyridine-3-carbaldehyde (CAS: 178488-37-4) can be synthesi...
178488-37-45-Methylimidazo[1,2-...
Compound Q&A
Are there alternatives to 2,4,6-Trihydroxyisophthalaldehyde (CAS: 4396-13-8) in synthesis?
There are alternative reagents that can be used in the synthesis of 2,4,6-Trihyd...
4396-13-82,4,6-Trihydroxyisop...
Compound Q&A
What is (2Z)-3-(5-Fluoro-1H-indol-3-yl)-2-sulfanylacrylic acid (CAS: 179461-52-0)?
(2Z)-3-(5-Fluoro-1H-indol-3-yl)-2-sulfanylacrylic acid is a chemical compound wi...
179461-52-0(2Z)-3-(5-Fluoro-1H-...
Source Journal
Organic & Biomolecular Chemistry
CiteScore:
3.4
Self-citation Rate:
10.3%
Articles per Year:
1041
Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.
Recommended Compounds
5-Amino-1-(2,4-difluorophenyl)-3-methyl-1H-pyrazole-4-carbonitrile
CAS Number:
1020057-92-4
Molecular Formula:
C11H8F2N4
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.