IR-High resolution spectroscopy of the N2O dimer: The torsional mode
Literature Information
A. Hecker, I. Scheele, M. Havenith
The rotational resolved IR-spectrum of the N2O–N2O van der Waals complex has been observed in the region of 2244–2252 cm−1 using a computer controlled lead salt diode laser spectrometer. This paper reports on the first observation of a van der Waals mode in (N2O)2. 1569 absorption lines could be assigned to the combination of the fundamental ν3-asymmetric stretch of N2O-monomer with the νtor-van der Waals mode (torsion) of the N2O-dimer. The band origin of the spectrum is observed at ν0 = 2247.83 cm−1 which is 20.0 cm−1 above the ν3 excitation of the N2O dimer. This deviates considerably from the theoretically predicted value at 37.84 cm−1 (C. Dutton, )
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