The role of the counteranion in the cation-π interaction
Literature Information
Publication Date
2003-03-10
DOI
10.1039/B300693J
Impact Factor
6.222
Authors
Christopher A. Hunter, Caroline M. R. Low, Carmen Rotger, Jeremy G. Vinter, Cristiano Zonta
View Original
Abstract
Chemical double mutant cycles have been used to quantify cation-π interactions in chloroform as a function of the nature of the counteranion. The cation-π interaction is −2.5 ± 0.4 kJ mol−1 and independent of the anion, even though the overall stability of the complexes varies by an order of magnitude due to competition of the anion for alternative binding sites.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry
Recommended Compounds
2-Methyl-2-propanyl (1-cyclobutyl-3-hydroxy-2-propanyl)carbamate
CAS Number:
816429-99-9
Molecular Formula:
C12H23NO3
![3-[7-Amino-3-(3-pyridinyl)pyrazolo[1,5-a]pyrimidin-6-yl]phenol structure](https://static.chemtradehub.com/structs/861/861249-77-6-025b.webp "3-[7-Amino-3-(3-pyridinyl)pyrazolo[1,5-a]pyrimidin-6-yl]phenol structure")
3-[7-Amino-3-(3-pyridinyl)pyrazolo[1,5-a]pyrimidin-6-yl]phenol
CAS Number:
861249-77-6
Molecular Formula:
C17H13N5O
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