Space charge conduction: Simple analytical solutions for ionic and mixed conductors and application to nanocrystalline ceria

Literature Information

Publication Date 2003-04-08
DOI 10.1039/B300170A
Impact Factor 3.676
Authors

Sangtae Kim, Jürgen Fleig, Joachim Maier


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Abstract

In this paper we present a set of simple analytical solutions for the parallel and the serial contributions of space charge zones to the overall conduction in bicrystals and (brick layered) ceramics for a variety of situations. The different situations are characterized by signs of the space charge potential, by different charge numbers of the carriers and by the presence or absence of acceptor or donor dopants. We can give solutions for arbitrary charge numbers as long as we restrict to sufficiently high space charge potentials and can presuppose equilibrium for the mobile carriers. A recent analysis of impedance measurements of nanocrystalline ceria based on a space charge model is briefly mentioned as a specific example, as it reflects the occurrence of highly n-conducting accumulation layers in addition to strongly blocking oxygen vacancy depletion layers.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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