An unprecedented trans-oriented product from the cleavage of a dipeptide
Literature Information
Manas K. Saha, Ivan Bernal
An unusual trans cleavage reaction was observed when trans-[Co(3,2,3-tet)Cl2]Cl {3,2,3-tet = N,N′-bis(3-aminopropyl)ethylenediamine}, was allowed to react with β-alanyl-L-histidine (a bioactive dipeptide) in an aqueous medium at pH ∼7.5 and 45 °C for 6 h.
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