Migratory insertion in N-heterocyclic carbene complexes of palladium; an experimental and DFT study

Literature Information

Publication Date 2003-02-24
DOI 10.1039/B212453J
Impact Factor 6.222
Authors

Andreas A. Danopoulos, Nikolaos Tsoureas, Jennifer C. Green, Michael B. Hursthouse


View Original

Abstract

The first authenticated example of migration of a methyl group from palladium(II) to a coordinated N-heterocyclic carbene is described.

Related Literature

Decarboxylative acylation of N-free indoles enabled by a catalytic amount of copper catalyst and liquid-assisted grinding

Jingbo Yu, Chao Zhang, Xinjie Yang, Weike Su

2019-04-06 Communication

DOI: 10.1039/C9OB00622B

The Lossen rearrangement from free hydroxamic acids

Mikaël Thomas, Jérôme Alsarraf, Nahla Araji, Isabelle Tranoy-Opalinski, Brigitte Renoux, Sébastien Papot

2019-05-08 Review Article

DOI: 10.1039/C9OB00789J

Transition metal-free α-Csp3–H oxidative sulfuration of benzyl thiosulfates with anilines to form N-aryl thioamides

Mengjun Qiao, Ling Chen, Fengyi Zhou, Yali Zhang, Lingfei Zhou

2019-03-19 Paper

DOI: 10.1039/C9OB00336C

Copper and palladium-catalyzed sequential reactions: one-pot synthesis of isoindolo[2,1-b]isoquinolin-7(5H)-ones

Hitesh Kumar Saini, Shiv Dhiman, Nitesh Kumar Nandwana, Rangan Krishnan, Anil Kumar

2019-03-26 Paper

DOI: 10.1039/C9OB00440H

Sarocladione, a unique 5,10:8,9-diseco-steroid from the deep-sea-derived fungus Sarocladium kiliense

Chun-Lan Xie, Jin-Mei Xia, Cui-Ping Xing, Zhu-Hua Luo, Zongze Shao, Xiao-Jun Yan, Shan He, Xian-Wen Yang

2019-05-29 Communication

DOI: 10.1039/C9OB01159E

Late stage functionalization of heterocycles using hypervalent iodine(iii) reagents

Rajnish Budhwan, Suman Yadav, Sandip Murarka

2019-06-10 Review Article

DOI: 10.1039/C9OB00694J

Front cover

Cover

DOI: 10.1039/C9OB90114K

The cubane paradigm in bioactive molecule discovery: further scope, limitations and the cyclooctatetraene complement‡

Sevan D. Houston, Tyler Fahrenhorst-Jones, Hui Xing, Benjamin A. Chalmers, Melissa L. Sykes, Jeanette E. Stok, Clementina Farfan Soto, Jed M. Burns, Paul V. Bernhardt, James J. De Voss, Glen M. Boyle, Maree T. Smith, John Tsanaktsidis, G. Paul Savage, Vicky M. Avery, Craig M. Williams

2019-06-26 Paper

DOI: 10.1039/C9OB01238A

You might also like

Compound Q&A

What are the main uses of (3.beta.)-3-Hydroxy-N,N-dimethyl-chol-5-en-24-amide (CAS: 79066-03-8)?

(3.beta.)-3-Hydroxy-N,N-dimethyl-chol-5-en-24-amide (CAS: 79066-03-8) is primari...

79066-03-8(3.beta.)-3-Hydroxy-...
Compound Q&A

What regulatory guidelines apply to 5-(aminomethyl)-2-methoxyphenol (CAS: 89702-89-6)?

5-(Aminomethyl)-2-methoxyphenol (CAS: 89702-89-6) is classified under GHS as a s...

89702-89-65-(aminomethyl)-2-me...
Compound Q&A

What is Thieno[2,3-c]pyridin-7(6H)-one (CAS: 28981-13-7)?

Thieno[2,3-c]pyridin-7(6H)-one (CAS: 28981-13-7) is a heterocyclic organic compo...

28981-13-7Thieno[2,3-c]pyridin...
Compound Q&A

Is 1-[(6-Methoxy-3-pyridinyl)methyl]-4-piperidinamine dihydrochloride (CAS: 1185311-28-7) safe?

1-[(6-Methoxy-3-pyridinyl)methyl]-4-piperidinamine dihydrochloride is generally ...

1185311-28-71-[(6-Methoxy-3-pyri...
Compound Q&A

What regulatory guidelines apply to [(2E)-3-Phenyl-2-propen-1-yl]phosphonic acid (CAS: 146404-58-2)?

[(2E)-3-Phenyl-2-propen-1-yl]phosphonic acid (CAS: 146404-58-2) is regulated und...

146404-58-2[(2E)-3-Phenyl-2-pro...
Compound Q&A

What regulatory guidelines apply to 6-Bromo-7-methoxyquinoline (CAS: 1620515-86-7)?

6-Bromo-7-methoxyquinoline (CAS: 1620515-86-7) falls under the scope of the Glob...

1620515-86-76-Bromo-7-methoxyqui...
Compound Q&A

What industries use (2R)-1-(1-Benzofuran-2-yl)-N-propyl-2-pentanamine (CAS: 260550-89-8)?

This compound is primarily used in the pharmaceutical industry for the developme...

260550-89-8(2R)-1-(1-Benzofuran...
1228013-15-71-Ethyl-7-[2-methyl-...
Compound Q&A

Are there alternatives to {5-(Acryloylamino)-2-[(dimethylamino)methyl]phenyl}boronic acid (CAS: 1217500-78-1) in synthesis?

Alternative reagents such as 2-[(dimethylamino)methyl]phenylboronic acid or rela...

1217500-78-1{5-(Acryloylamino)-2...
Compound Q&A

What is 3-(Piperidin-4-yloxy)pyridine (CAS: 310881-48-2)?

3-(Piperidin-4-yloxy)pyridine (CAS: 310881-48-2) is an organic compound with the...

310881-48-23-(Piperidin-4-yloxy...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.