Formal radical cyclization onto benzene rings—a general method proceeding via cross-conjugated dienones
Literature Information
Derrick L. J. Clive, Stephen P. Fletcher, (in part) Mingzhao Zhu
Cross-conjugated dienones of type 5 (X = I), which are readily available from phenols, undergo radical cyclization (5 → 6 → 7), and the products are easily aromatized (7 → 8), giving substances that are formally derived by radical cyclization onto a benzene ring (cf.eqn. (1)).
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